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Electrochemical oxidation of perfluoroalkenes in fluorosulfuric acid

โœ Scribed by D. Brunel; A. Calmettes; A. Germain; P. Moreau

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
51 KB
Volume
45
Category
Article
ISSN
0022-1139

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Electrochemical oxidation of organic com
Electrochemical oxidation of organic compounds in fluorosulfuric acidโ€”III. Voltammetric investigation of aromatic carboxylic acids and acylium ions
โœ A.P. Rudenko; M.Ja. Zarubin; N.S. Barsheva; F. Pragst ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 600 KB

The anodic behavior of a series of substiruted benzoic acids la -1w and of the corresponding benzoylium ions r is investigated by cyclic voltammetry in fluorosulfuzacid at -76%. The acids are oxidized to cation radicals, the stability of which decreases with decreasing number ofalkyi substituents. A