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Electrochemical oxidation of organosilicon compounds I. Oxidative cleavage of carbon-silicon bond in allylsilanes and benzylsilanes

✍ Scribed by Jun-ichi Yoshida; Toshiki Murata; Sachihiko Isoe


Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
221 KB
Volume
27
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Carbon silicon bond cleavage in the oxid
✍ Enrico Baciocchi; Tiziana Del Giacco; Cesare Rol; Giovanni Vittorio Sebastiani πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 234 KB

Benzyltrirrethylsilanes react with cerium(IV) ammonium nitrate in AcOH to give products -of C-Si cleavage (benzyl nitrate and acetate), under very mild conditions and in quantitative yields. The reaction rate is very sensitive to the nature of the ring substituents (y= -5.4), which clearly suggests