Electrochemical Oxidation of NH3 on Platinum Electrodeposited onto Graphite Electrode
✍ Scribed by Le Vot, Steven; Reyter, David; Roué, Lionel; Bélanger, Daniel
- Book ID
- 121718260
- Publisher
- The Electrochemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 215 KB
- Volume
- 159
- Category
- Article
- ISSN
- 0013-4651
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The electrochemical oxidation of ammonia (NH 4 + /NH 3 ) in sodium perchlorate was investigated on IrO 2 electrodes prepared by two techniques: the thermal decomposition of H 2 IrCl 6 precursor and the anodic oxidation of metallic iridium. The electrochemical behaviour of Ir(IV)/Ir(III) surface redo
On-line mass spectrometry is used to examine the kinetics of NH,-oxidation on polycrystalline Pt wires for temperatures between 250 and 1500°C. A differentially pumped system is employed so that species concentrations can be continuously monitored and absolute reaction rates determined. Reactions st