Electrochemical oxidation of 4-morpholinoaniline in aqueous solutions: Synthesis of a new trimer of 4-morpholinoaniline
β Scribed by Roya Esmaili; Davood Nematollahi
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 406 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
β¦ Synopsis
Electrochemical oxidation of 4-morpholinoaniline has been studied in various pHs using cyclic voltammetry and controlled-potential coulometry. The electrochemical trimerization of 4-morpholinoaniline is described and its mechanism has been studied in aqueous solution. This method provides a green, reagent-less, and environmentally friendly procedure with high atom economy, for the synthesis of "4-morpholinoaniline-trimer" using a carbon electrode in an undivided cell in good yield and purity.
π SIMILAR VOLUMES
The electrochemical oxidation of the 2,4-dibromoaniline in aqueous sulphuric acid solutions at concentrations higher than l.OM, at a Pt electrode, has been studied by rotating-disk electrode, cyclic voltammetry and controlled-potential electrolysis. A single oxidation process is found at acid concen
Reduction of KMnO 4 with KBH 4 in aqueous solutions has been investigated systematically at ambient temperatures as a function of reaction pH and the volume of borohydride. The products are characterized by X-ray diffraction, transmission electron microscopy, atomic absorption spectroscopy, redox ti
Kolbe-type electrolysis. Optically pure 4-acetoxy-3-[l-(t-butyldimethylsiloxy)ethyl]-2azetidinone, which is an important intermediate for the synthesis of thienamycin, and (+)-PS-5 were synthesized by use of this method. We have already reported the new synthesis of 4-acetoxy-P-lactams by use of el