The electrochemical oxidation of 2-phenyl-l,2-benzisothiazoi-3(2H)-ones and related compounds was studied by conventional and microelectrode techniques. Hammett plots were drawn for a series of N-aryl substituted 2-phenyl-l,2-benzisothiazol-3-(2H)-ones and compared with those of the selenium analogu
Electrochemical oxidation of 2-phenyl-1,2-benzisothiazol-3(2H)-one and related open-chain compounds in acetonitrile
✍ Scribed by B. Dakova; R. Müller; L. Lamberts; M. Evers
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 617 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
The electrochemical oxidation of 2-phenyl-1,2-benxisothiaxol-3(2H)-ones and related compounds in acetonitrile solution was studied by voltatnmetry using a rotating platinum electrode, cyclic voltammetry, controlled Potential coulometry and electrolysis. Further oxidation of studied compounds gave the corresponding sulfoxide. Comparison of the cyclic compound and related open-chain compounds was discussed.
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