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Electrochemical investigation of the α/ß-phase transition of silver sulfide

✍ Scribed by H. Wysk; H. Schmalzried

Book ID
104296481
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
563 KB
Volume
96
Category
Article
ISSN
0167-2738

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✦ Synopsis

The kinetics of the temperature induced &P-phase transition of silver sulfide has been investigated using solid galvanic cells of the type Ag 1 o-AgI 1 Ag,S. Single precipitation events have been observed during the p + cx transformation, where 01 indicates the low temperature modification. The nucleation free enthalpy of excess silver in Ag,+,S has been determined and the influence of elastic stress in the Ag precipitation process is considered.

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The kinetics of the anodic formation and reduction of phase silver sulfide films on silver in aqueous sulfide solutions
✍ Viola I. Birss; Graham A. Wright 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 696 KB

The kinetics of the potentiodynamic formation and reduction of silver sulfide films on a silver rotating disc electrode in aqueous sulfide solutions were investigated . Due to the inherently fast reaction between silver and the HS -species, the physical processes of migration and diffusion of ions i