## Abstract Pd(DME)Cl~2~ complex was synthesized and characterized, where DME is 2‐{[2‐(dimethylamino)ethyl]‐methylamino}ethanol. Stoichiometry and stability constants of the complexes formed between various biologically relevant ligands (amino acids, peptides, DNA constituents, and dicarboxylic ac
Electrochemical Investigation of the Commercial Iron Sulfide Stick—Interaction with Complexing Ligands
✍ Scribed by R. Renuka; J.Isac Ruben
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 216 KB
- Volume
- 233
- Category
- Article
- ISSN
- 0021-9797
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✦ Synopsis
The present work aims to examine iron sulfide for its interfacial properties in aqueous media containing different ionic/complexing agents. The primary experimental investigation is the potentiometric response of the commercial iron sulfide stick in various aqueous media supplemented by cyclic voltammetry and UV-visible and IR spectroscopy. The significance of employing the commercial iron sulfide stick is that it is quite stable under ordinary conditions and possesses appreciable conductivity for employing it as an electrode.
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## Abstract The ligand __N,N′__‐bis(6‐methyl‐2‐pyridylmethyl)‐__N,N′__‐bis(2‐pyridylmethyl)ethane‐1,2‐diamine (L~6~^2^2M) has allowed to prepare the new Fe^II^ complex [(L~6~^2^2M)FeCl~2~] (1), and to compare its structural and spectroscopic characteristics with [(L~6~^2^2M)FeCl]PF~6~ (2). The mole