Electrochemical Investigation of Oxygen Intercalation into La2CuO4+δPhases

✍ Scribed by E. Magnone; G. Cerisola; M. Ferretti; A. Barbucci

• Publisher: Elsevier Science
• Year: 1999
• Tongue: English
• Weight: 238 KB
• Volume: 144
• Category: Article
• ISSN: 0022-4596
• DOI: 10.1006/jssc.1998.7970

✦ Synopsis

In this work the electrochemical intercalation of oxygen in La 2 CuO 4 phases has been studied. Oxygen intercalation has been performed at different anodic potentials for fixed time in alkaline solution (1 M NaOH) at room temperature. The electrochemistry of the phenomena taking place at the oxide-solution interface has been investigated by cyclic voltammetry (CV), controlledpotential coulometry, and electrochemical impedance spectroscopy (EIS). The homogeneity of processed samples and the lattice parameters prior to and after oxygen intercalation have been verified by X-ray powder diffraction. SEM has been used to relate surface modification to the potential applied after electrochemical oxygen intercalation. The recent theories and knowledge of mechanisms of oxygen intercalation into the oxide lattice have been related to the experimental results. Oxygen intercalation seems to occur at potentials slightly lower than that of the oxygen evolution reaction (OER) and proceeds on a parallel pathway to O 2 evolution at more anodic potentials.