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Electrochemical intercalation into graphite seen as an electrocapillary process

✍ Scribed by Ahmed Harrach; André Métrot


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
418 KB
Volume
34
Category
Article
ISSN
0013-4686

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✦ Synopsis


The electrochemical intercalation of H,SO, into graphite leads to the well known graphite salts CT HSO, xH,SO, (with n-+20), x -2.5). The potential-charge relations observed during intercalation agree well with a model involving the extended graphene layer-intercalate interfacial capacitance. The components of this capacitance are studied, including the effect of Fermi level lowering. A computed electrocapillary curve is compared to the separation work of graphenc layers.