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Electrochemical hydrodimerization of carbonyl compounds in aprotic media

✍ Scribed by V. P. Gul'tyai; A. S. Mendkovich; T. Ya. Rubinskaya

Book ID
112561890
Publisher
Springer
Year
1987
Tongue
English
Weight
387 KB
Volume
36
Category
Article
ISSN
1573-9171

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✍ Jacques Delaunay; Armelle Orliac-Le Moing; Jacques Simonet πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 184 KB

Aryltritylketones ArCOR were reduced in aprotic deoxygenated dimethylformam ide. Product distribution after electrolysis showed the formation of a diester involving the solvent and the formation of ACO' provoked by the seission of the C-C bond of the anion radical. This kind of cleavage is somewhat