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Electrochemical growth of spherical clusters under joint ohmic, diffusion and ion transfer limitations—III

✍ Scribed by Emilia Michailova; Alexander Milchev

Book ID
103062502
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
184 KB
Volume
37
Category
Article
ISSN
0013-4686

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✦ Synopsis

The paper presents the results of an experimental study of the growth kinetics of single silver crystals electrochemically deposited on a platinum substrate. It is shown that the growth mechanism obeys the kinetic law derived for the case of joint ohmic, diffusion and ion transfer limitations in the presence of a specified quantity of supporting electrolyte. Data are obtained for the diffusion coefficient and for the exchange current density of silver in aqueous solution of silver nitrate.

📜 SIMILAR VOLUMES

Electrochemical growth of spherical clus
Electrochemical growth of spherical clusters under joint ohmic, diffusion and ion transfer limitations—II
✍ Alexander Milchev 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 346 KB

Ahstrati-The paper suggests a theoretical consideration of the growth kinetics of spherical clusters in the presence of an arbitrary quantity of supporting electrolyte. It is shown that even low concentrations of non-depositing electroactive species in the basic electrolyte may significantly reduce