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Electrochemical fluorination of 3-alkylidenes

✍ Scribed by Eliane Laurent; Hélène Lefranc; Robert Tardivel; Abdelkader Bensadat; Hassiba Benotmane


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
63 KB
Volume
35
Category
Article
ISSN
0022-1139

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Electrochemical fluorination of methyl c
✍ Wojciech Dmowski; Tomasz Kozłowski 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 821 KB

Methyl cinnamates, R-CsH&H~H-COrCH, (R = CHjO, CH3, H, F and CF,), were electrochemically fluorinated in a 1 M solution of (CzH5)jN. 3HF in acetonitrile under potentiostatic conditions. The electrolyses gave, in general, diasteroisomeric mixtures of 2,3-difluoro-3-phenylpropionates (2), 3-acetamido-