Electrochemical epoxidation of olefins
โ Scribed by J.M. van der Eijk; Th.J. Peters; N. de Wit; H.A. Colijn
- Book ID
- 103935259
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 405 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0920-5861
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๐ SIMILAR VOLUMES
A-Electroge&tatad and ngeneratad ailver(III)oxo bia(23'-bipyridine) and similar complexes can act as redox catalysts for the indirect electrochemical epoxidation of electmn-deficient oletins in aqueous ace&m&rile. Thus, isobutyl methacryMe is electmlyaed to form 'the epoxide with 87% material yield
## By analogy between the 0x0 forms of vanadium (V) and iron (IV). the latter being the active species in oxkiations by cytochrome P-450, the system constituted by vanadium oxide (catalyst) and t-butylhydroperoxiak (oxidant) gives good results in the conversion of ol@s to the corresponding epoxide