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Electrochemical cross-coupling of organic halides: Trichloromethylation and related synthesis of gem-dichloro compounds

✍ Scribed by J.Y. Nédélec; H. Ait-Haddou-Mouloud; J.C. Folest; J. Périchon

Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
130 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis

Tlze cta.As-coupling oj activated &kg1 haCdea ukth carbon t&th.ach~Zohide o& AubA,tituted tich1o~omcti~ane, can be obtined &ec.tiochemkaUy in good y-i&d in an undkkded CCC&Z with a Aachi&iciak? anode.

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Polymer-bound palladium-catalyzed cross-
Polymer-bound palladium-catalyzed cross-coupling of organoboron compounds with organic halides and organic triflates
✍ Su-Bum Jang 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 198 KB

The polymer-bound palladium-catalyzed cross-coupling reaction of electrophiles(i.e., halides and triflates) with organoboron compounds to form carbon-carbon bonds was achieved at mild conditions with very high activity in the Suzuki coupling reaction. The polymeric catalyst can be easily separated f