The electrochemical oxidation of a high surface area carbon black (1000 m2/g) was investigated in 96% H,PO, at 135ยฐC. The total anodic current, the amount of CO, evolved and the oxygen content of the carbon were all measured as a function of time and potential. Two anodic processes occurred: the for
Electrochemical corrosion behavior of carbon black in phosphoric acid
โ Scribed by P.L. Antonucci; F. Romeo; M. Minutoli; E. Alderucci; N. Giordano
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 503 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0008-6223
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โฆ Synopsis
Several carbon blacks, widely differing in surface and bulk characteristics, have been subjected to potentiostatic corrosion tests (1 V RHE) in H,POI at different temperatures. Corrosion currents and calculated carbon weight losses are shown as a function of time. It is confirmed that log (corrosion current) is directly related to log (time on stream) for the duration of the test. The surface area of different blacks relates linearly to measured corrosion currents. Examination of the normalized corrosion currents vs pH of the slurry shows a volcano-shaped correlation with maximum corrosion at pH = 8.
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