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Electrochemical Control of CO/NO Ligand Exchange in a Triruthenium Cluster Monolayer Assembled on a Gold Electrode Surface

✍ Scribed by Ye, Shen; Zhou, Wei; Abe, Masaaki; Nishida, Takuma; Cui, Longfei; Uosaki, Kohei; Osawa, Masatoshi; Sasaki, Yoichi

Book ID
126398208
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
63 KB
Volume
126
Category
Article
ISSN
0002-7863

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Oxidation States and CO Ligand Exchange
Oxidation States and CO Ligand Exchange Kinetics in a Self-Assembled Monolayer of a Triruthenium Cluster Studied by In Situ Infrared Spectroscopy
✍ Wei Zhou; Shen Ye; Masaaki Abe; Takuma Nishida; Kohei Uosaki; Masatoshi Osawa; Y πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 321 KB πŸ‘ 1 views

## Abstract Oxidation states and CO ligand exchange kinetics in a self‐assembled monolayer (SAM) of an oxo‐centered triruthenium cluster [Ru~3~(ΞΌ~3~‐O)(μ‐CH~3~COO)~6~(CO)(L^1^)(L^2^)] (L^1^ = [(NC~5~H~4~)CH~2~NHC(O)(CH~2~)~10~S‐]~2~, L^2^ = 4‐methylpyridine) have been extensively investigated on th