Electrochemical Activation Parameters of Coupled Electron-Transfer and Spin-Exchange Reactions. Experimental Studies of [M(Tacn) 2 ] 3+/2+ and [Fe(Pzb) 2 ] +/0 Redox Systems

Theoretical study of self-exchange elect

Theoretical study of self-exchange electron-transfer reactions for the M(H2O)3.0.CO;2-J/asset/equation/tex2gif-ueqn-1.gif?v=1&t=h5o1nw4g&s=1376fb9f38de599480e9d63bb7cf311e3f6f276f" class="inlineGraphic"> (M = V, Cr, Mn, and Fe) systems

✍ Dongju Zhang; Bingyou Zhuang; Dacheng Feng; Chengbu Liu 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 400 KB 👁 2 views

Based on an activation model, a available scheme to calculate the rate of the electron-transfer reaction between transition-metal complexes in aqueous solution is presented. Ab initio technique is used to determine the electron-transfer reactivity of the type M(H 2 O) 2+/3+ 6 of transition-metal com