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Electrocatalyzed Trimerization of Isocyanates to Hexahydro-s-Triazinetriones

โœ Scribed by Carelli, Vincenzo; Liberatore, Felice; Moracci, Franco Micheletti; Tortorella, Silvano; Carelli, Italo; Inesi, Achille


Book ID
118234737
Publisher
Taylor and Francis Group
Year
1985
Tongue
English
Weight
327 KB
Volume
15
Category
Article
ISSN
0039-7911

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Effect of polar aprotic solvents on the
โœ S. Dahi; A. Zilkha ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 271 KB

The polymerization of aliphatic isocyanates by organometallic catalysts such as tributyltin oxide, Ti(OBuh or Zr(OBu),, was slow and no enhancement in rate was found on addition of DMF or DMSO, contrary to what was found with PhNCO. However, similar to the latter, fast reactions were observed with c