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Electrocatalytic transformation of malononitrile and cycloalkylidenemalononitriles into spirotricyclic and spirotetracyclic compounds containing cyclopropane and pyrroline fragments

✍ Scribed by M.N. Elinson; S.K. Fedukovich; T.A. Zaimovskaya; A.N. Vereshchagin; G.I. Nikishin


Book ID
111607492
Publisher
Springer
Year
2003
Tongue
English
Weight
471 KB
Volume
52
Category
Article
ISSN
1573-9171

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Electrochemical Transformation of Malono
✍ Michail N. Elinson; Sergey K. Feducovich; Tatiana L. Lizunova; Gennady I. Nikish πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 169 KB

AbstractÐElectrolysis of malononitrile and carbonyl compounds in the presence of alkali metal halides in an undivided cell results in the formation of substituted 1,1,2,2-tetracyanocyclopropanes in 60±90% yield. This electrocatalytic variant of the Wideqvist reaction using malononitrile instead of b