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Electrocatalytic reduction of nitrite by copper complexes of 1,10-phenanthroline and 2,2′:6′,2″-terpyridine

✍ Scribed by Chun-Sing Fung; Kwok-Yin Wong

Publisher
Elsevier
Year
1996
Tongue
English
Weight
432 KB
Volume
401
Category
Article
ISSN
1572-6657

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2,2′-Bipyridine,1,10-phenanthroline and
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The reactions of Ga(NO 3 ) 3 AE 9H 2 O with 2,2 0 -bipyridine (bpy), 1,10-phenanthroline (phen) and 2,2 0 :6 0 ,2 00 -terpyridine (terpy) in alcohols afford the complexes [Ga 2 (OH) 2 (bpy) 4 ](NO 3 ) 4 (1), [Ga 2 (OH) 2 (phen) 4 ](NO 3 ) 4 (2) and [Ga 2 (OH) 2 (H 2 O) 2 (terpy) 2 ](NO 3 ) 4 (3), re

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The synthesis of a ligand including a 1,10-phenanthroline and a 2,2%:6%,2¦-terpyridine separated by a 1,3-phenylene spacer is presented. The different aromatic carbon carbon bonds have been generated by reactions with organolithium compounds, and by Stille and Suzuki couplings.

ChemInform Abstract: Synthesis of Multif
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