Electrochemical proton reduction was catalysed by zinc phthalocyanine ( ZnPc ) incorporated in a Nafion or poly(4-vinylpyridine-co-styrene) (P(VP-St)) film coated on a graphite electrode. The turnover number (TN) of the complex to catalyse H ~2~ evolution was 10^4^ h^-1^. The TN of Nafion[ ZnPc ] wa
✦ LIBER ✦
Electrocatalytic proton reduction by phthalocyanine cobalt derivatives incorporated in poly(4-vinylpyridine-co-styrene) film
✍ Scribed by Feng Zhao; Jian Zhang; Toshiyuki Abe; Dieter Wöhrle; Masao Kaneko
- Book ID
- 104424408
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 411 KB
- Volume
- 145
- Category
- Article
- ISSN
- 1381-1169
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Potential step chronoamperospectrometry (PSCAS) measurement was carried out to investigate the one-electron transfer in the reduction of tetraphenylporphyrin cobalt(III) ([Co III TPP(À2)] ) incorporated into a Nafion or poly(4-vinylpyridine-co-styrene) (P(VP-St)) film coated on an ITO electrode. The