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Electrocatalytic oxidation of olefines and ketones based on a RuIV = O/RuII-H2O system.

✍ Scribed by João Marcus Madurro; Glaico Chiericato Jr.; Wagner F. De Giovani; José Ricardo Romero

Book ID: 104216450
Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 228 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)80204-x

No coin nor oath required. For personal study only.

✦ Synopsis

An electrocatalytic procedure is described for the oxidation ofcyclohexene, safrole, isosafrole, isophorone, deoxybenxoin and acetophenone using the Ru IV oxidant

[RI?" (trpy)(bpy)Ol'+. The relative reactivities of the substrates are presented.

Polypyridyl complexes of ruthenium have a rich synthetic' and redox chemistry2.

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