๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Electrocatalytic oxidation of formic acid on ultrafine palladium particles supported on a glassy carbon

โœ Scribed by Xiao-Gang Zhang; Toshihide Arikawa; Yasushi Murakami; Kiyochika Yahikozawa; Yoshio Takasu

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
710 KB
Volume
40
Category
Article
ISSN
0013-4686

No coin nor oath required. For personal study only.

โœฆ Synopsis

The effect of particle size of ultrafine palladium particles on the electrochemical oxidation of formic acid in a perchloric acid solution has been investigated by cyclic voltammetry (CV) and differential electrochemical mass spectroscopy (DEMS). Except in the hydrogen sorption&sorption region, only carbon dioxide was observed by the DEMS as an oxidation product, and the profile of the i,,,-E curve was in fair agreement with that of i-E curves. With a decrease in the palladium particle size, the specific activity of the palladium particles for the oxidation of formic acid gradually increased until cc. 3 nm in the mean diameter, and then it steeply decreased.

๐Ÿ“œ SIMILAR VOLUMES

Electrocatalytic oxidation of formaldehy
Electrocatalytic oxidation of formaldehyde on ultrafine palladium particles supported on a glassy carbon
โœ Xiao-Gang Zhang; Yasushi Murakami; Kiyochika Yahikozawa; Yoshio Takasu ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 470 KB

The effect of the particle size of ultrafine palladium particles supported on a flat and dense glassy carbon on the electrochemical oxidation of formaldehyde in a perchloric acid solution has been investigated by cyclic voltammetry (CV) and differential electrochemical mass spectroscopy (DEMS). A ma

Electrocatalytic properties of ultrafine
Electrocatalytic properties of ultrafine gold particles supported onto glassy carbon substrates toward formaldehyde oxidation in alkaline media
โœ Kiyochika Yahikozawa; Katsunori Nishimura; Mari Kumazawa; Naokazu Tateishi; Yosh ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 912 KB

Ultrafine Au particles were supported on flat glassy carbon substrates with fine dispersion, by means of the vacuum evaporation technique. Highest activities toward the HCHO oxidation in alkaline media were obtained with the electrodes of intermediate amounts of Au deposited.

Kinetic study of formic acid oxidation o
Kinetic study of formic acid oxidation on carbon supported Pd electrocatalyst
โœ Yujiao Wang; Bing Wu; Ying Gao; Yawen Tang; Tianhong Lu; Wei Xing; Changpeng Liu ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 504 KB

The oxidation of formic acid at the Pd/C catalyst electrode is a completely irreversible kinetic process with the reaction order of 1.0. The oxidation rate of formic acid is increased with increasing the concentration of formic acid and is decreased with increasing H + concentration. The apparent ne