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Electrocatalytic four-electron reduction of oxygen with Copper (II)-based metal-organic frameworks

✍ Scribed by Junjie Mao; Lifen Yang; Ping Yu; Xianwen Wei; Lanqun Mao


Book ID
113596057
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
539 KB
Volume
19
Category
Article
ISSN
1388-2481

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## Abstract The reaction of CuCl~2~**·**2H~2~O with three novel ditopic ligands, 2‐methyl‐1,4‐benzeneditetrazolate (MeBDT^2–^), 4,4′‐biphenylditetrazolate (BPDT^2–^), and 2,3,5,6‐tetrafluoro‐1,4‐benzeneditriazolate (TFBDTri^2–^), affords the metal–organic frameworks Cu(MeBDT)(dmf) (**1**), Cu(BPDT)