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Electrocatalysis in the electrochemical conversion/combustion of organic pollutants for waste water treatment

โœ Scribed by Christos Comninellis

Book ID
103067005
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
609 KB
Volume
39
Category
Article
ISSN
0013-4686

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โœฆ Synopsis

Abstrsti-The electrochemical oxidation (or combustion) of organ& with simultaneous oxygen evolution has been investigated using different electrode material (Pt, Ti/lrO,, Ti/SnO,). A simplified mechanism for the electrochemical oxidation or combustion of organics is presented according to which selective oxidation occurs with oxide anodes (MO,) forming the so-called higher oxide MO,,, and combustion occurs with electrodes at the surface oflwhich 'dH radicals are accumulated. Detection of 'OH radicals formed by water discharge at different anodes using N,Ndimethyl-p-nitrosoaniline (RNO) as a spin trap and preparative electrolysis confirm the proposed mechanism.

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