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Electro-organic reactions. Part 13. The anodic acetoxylation of methyl oleate

✍ Scribed by Adams, Chitra; Frankel, Edwin N.; Utley, James H. P.

Book ID
111867129
Publisher
Royal Society of Chemistry
Year
1979
Weight
486 KB
Volume
0
Category
Article
ISSN
1472-7781

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Electro-organic reactionsβ€”14. The intram
Electro-organic reactionsβ€”14. The intramolecular cathodic cyclization of abscisic acid methyl ester
✍ Bulent Terem; James H.P. Utley πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 English βš– 365 KB

Abs&act -Abscisic acid methyl ester (1) is reduced smoothly at controlled potential at a mercury cathode in a 2 F mol-' reaction which gives the bicyclic ester (5) in good yield. Cyclic voltammetry of (1). and several related model compounds, reveals that the C-6 hydroxyl group precludes conjugation