Electrically enhanced enzymic hydrolysis of vegetable oils using lipase from Candida rugosa

Co-solvent enhancement of enantioselecti

Co-solvent enhancement of enantioselectivity in lipase-catalysed hydrolysis of racemic esters. A process for production of homochiral C-3 building blocks using lipase B from Candida antarctica

✍ Trond Vidar Hansen; Viggo Waagen; Vassilia Partali; Henrik W Anthonsen; Thorleif 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 306 KB

Lipase-catalysed hydrolysis of butanoates of 3-methoxy-1-(phenylmethoxy)-2-propanol and 3-chloro-l-(phenylmethoxy)-2-propanol with various lipases gave low enantioselectivity, E. By additon of water miscible organic cosolvents, in particular tert-butanol and acetone, the E-value was raised from 7 to