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Electrically controlled anionic polymerization of methyl methacrylate

✍ Scribed by Funt, B. L. ;Bhadani, S. N.

Publisher
Wiley (John Wiley & Sons)
Year
1965
Tongue
English
Weight
431 KB
Volume
3
Category
Article
ISSN
0449-2951

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## Abstract Methyl methacrylate (MMA) was polymerized by thiophenol without oxidants. Hydroquinone had no effect on the polymerization, indicating that the polymerization proceeded via a non‐radical process. Since other monomers with an __x__,β‐unsaturated carbonyl group polymerized similarly, the

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A novel ionic polymerization of methyl methacrylate (MMA) with a series of enamines (1) in the presence of methylaluminum bis(2,6-di-tert-butylphenoxide) (2) was examined. Both nucleophile (1) and electrophile (2) are indispensable for the present polymerization, in which (1) acts as initiator and (