Mixed valencies system Sr 1Àx La x PbO 3Àd (0 6 x 6 0.15) has been prepared by solid state reaction at 900 °C. All solutions crystallize in a distorted perovskite structure and were carefully examined by chemical analysis and X-ray diffraction. The La 3+ -substitution was checked via the linear depe
Electrical resistivity of the perovskite Ba1−xKxBiO3 (x ⩽ 0.15) under high pressure
✍ Scribed by Yoshinori Imai; Masatsune Kato; Takashi Noji; Yoji Koike; Masato Hedo; Yoshiya Uwatoko; Nobuo Mori
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 110 KB
- Volume
- 426-431
- Category
- Article
- ISSN
- 0921-4534
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✦ Synopsis
Electrical resistivity measurements of the insulating Ba 1Àx K x BiO 3 (x = 0, 0.15) under high pressure up to 8 GPa have been performed in order to search for the pressure-induced superconductivity, using a cubic-anvil pressure system. A polycrystal of BaBiO 3 has been prepared by the solid-state reaction method. A single crystal of Ba 0.85 K 0.15 BiO 3 has been synthesized by the electrochemical method from molten salts. The electrical resistivity of both compounds slightly decreases with increasing pressure. However, the temperature dependence still remains semiconductive and no superconductivity is observed.
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