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Electrical properties of polyaniline–polystyrene blends above the percolation threshold

✍ Scribed by V. Jousseaume; M. Morsli; A. Bonnet; O. Tesson; S. Lefrant

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
122 KB
Volume
67
Category
Article
ISSN
0021-8995

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✦ Synopsis

Blends of conductive polymers with classical ones can exhibit good mechanical properties and good electrical conductivity and deserve great attention for application in electronic industrial technology. Conductive polyaniline solutions have been chemically prepared using bis(2-ethyl hexyl)hydrogen phosphate (DiOHP) as the dopant chemical species. The codissolution method leads to conductive polyanilinepolystyrene (PANI-PSt) composites with good mechanical properties. The dependence of electrical conductivity on the volume fraction of PANI in the blend is found to be characteristic of a percolation system. Electrical conductivity and thermoelectric power measurements are interpreted on the basis of hopping mechanisms between polaronic clusters.

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