Electrical Properties and Structure of the Organic Metallic Compound bis (tetraselenotetracene)-iodide, (TSeT)2-I

✍ Scribed by Bruno Hilti; Carl W. Mayer; Mrs. Grety Rihs

• Publisher: John Wiley and Sons
• Year: 1978
• Tongue: German
• Weight: 343 KB
• Volume: 61
• Category: Article
• ISSN: 0018-019X
• DOI: 10.1002/hlca.19780610430

✦ Synopsis

The preparation of the new organic metallic compound (TSeT)2-I is reported. The crystal structure of the free donor, TSeT, is discussed and compared with the crystal structure of (TSeT)2-I. The latter has the orthorhombic space group P2,212 and hence is not isomorphous with the analogous compounds (TSeT),-Cl and (TSeT)2-Br, described by Shchegolev et al. .

In contrast to those complexes (TSeT)*-I consists of only one set of crystallographically equivalent chains and therefore its transition to the low-temperature conducting state (Fig. ) is also of different type.

to 1.5 .