Electrical mobilities in equimolar mixtures of CdCl2 with NaCl, KCl and CsCl
✍ Scribed by J.C.Th. Kwak; J.A.A. Ketelaar
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- English
- Weight
- 327 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
Ionic mobilities of the three constituent ions have been measured at different temperatures in the molten equimolar mixtures CdCI,-NaCI (430-55O"C), CdCl,-KC1 (450-540°C) and CdCl,-CsCl (540-6OO"C) with a radiotracer-electrophoresis method. l15Cd, a2Na, 1*7Cs and YJl radioisotopes were used. The equivalent conductances of the CdC&-NaCl and CdCl&Xl calculated from the ionic mobilities agree with the literature data for A.
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The electrochemical reduction of Ti4 + ions in equimolar KCI-NaCl melts containing less K,TiFd (lwt %) on a Pt electrode, was studied at 973 K by means of linear sweep voltammetry, stationary current density-potential curve and ac impedance methods. It was found that the reduction of Ti4+ ions in th