The electrical and mechanical properties of new conductive rubber composites based on ethylene-propylene-diene rubber, acrylonitrile butadiene rubber (NBR), and their 50/50 (weight ratio) blend filled with conductive black were investigated. The threshold concentrations for achieving high conductivi
Electrical conductivity of carbon black and carbon fibre filled silicone rubber composites
✍ Scribed by Sau, K. P. ;Khastgir, D. ;Chaki, T. K.
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 76 KB
- Volume
- 258
- Category
- Article
- ISSN
- 0003-3146
No coin nor oath required. For personal study only.
✦ Synopsis
Electrically conductive silicone rubber composites have been prepared through incorporation of conductive acetylene black and short carbon fibre (SCF). The percolation limit for the attainment of high conductivity is found to be relatively less for silicone rubber based composites compared to EPDM or NBR based composites reported earlier. Percolation limit is found to be lower for SCF-filled systems (7.5 phr) compared to black-filled ones (14 phr). Both black-and SCF-filled systems exhibit an increase in resistivity with the increase in temperature (PCT effect). This PCT effect may be explained in terms of differences in the thermal expansion between the rubber matrix and the conductive filler. However, resistivity-versus-temperature plots are not identical during the heating-cooling cycle, leading to some hysteresis and electrical set. The current-voltage relationship is linear (Ohmic in nature) at room temperature but becomes non-linear (non-Ohmic) at elevated temperatures. The resistivity of these composites is measured under different conditions such as on applying pressure and being subjected to different mechanical stress and strain over the specimens. An effort has been made to correlate the effect of different parameters on electrical resistivity with the change in the conductive network structure under different conditions. ZUSAMMENFASSUNG: Elektrisch leitende Silikonkautschuk-Verbundwerkstoffe wurden durch Fu ¨llen mit leitfa ¨higem Acetylenruß bzw. kurzen Kohlenstoffasern (SCF) hergestellt. Die Perkolationsgrenze fu ¨r das Erreichen einer hohen Leitfa ¨higkeit liegt bei Silikonkautschuk-Verbundwerkstoffen relativ niedrig im Vergleich zu den bereits beschriebenen Verbundwerkstoffen auf EPDM-oder NBR-Basis. Die Perkolationsgrenze ist bei den SCF-gefu ¨llten (7.5 phr) Systemen niedriger als bei den mit Ruß (14 phr) gefu ¨llten. Sowohl die rußgefu ¨llten als auch die SCF-gefu ¨llten Systeme zeigen eine Erho ¨hung des spezifischen Widerstands mit der Temperatur (PCT-Effekt). Dieser PCT-Effekt kann mit dem unterschiedlichen thermischen
📜 SIMILAR VOLUMES
The conductivity mechanism for a carbon black (CB) filled high-density polyethylene (HDPE) compound was investigated in this work. From the experimental results obtained, it can be seen that the relation between electrical current density (J) and applied voltage across the sample (v) coincides with
The a.c. electrical properties of graphitized carbon-black Ðlled rubbers were investigated in the temperature range 25È85¡C and in the frequency range 10È106 Hz. The volume fraction of the Ðller varied from 15 to 60%. The a.c. impedance was found to decrease dramatically with increasing Ðller conten
The polyurethane composites with conducting carbon black (CB) were prepared by a solution-precipitation process, which was followed by melt compression molding. The polyurethane used has good shape memory effect. The morphology of CB fillers in polyurethane matrix and the resulting conductivity of t