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Electrical and interfacial properties of a Li3Fe2(PO4)3 single crystal with silver electrodes

✍ Scribed by A.K. Ivanov-Schitz; J. Schoonman

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 550 KB
Volume: 91
Category: Article
ISSN: 0167-2738
DOI: 10.1016/s0167-2738(96)00415-8

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✦ Synopsis

Electrical conductivity and thermal properties of Li,Fe,(PO,), single crystals have been studied over a wide temperature range. The phase transformation detected at 483 K by DSC is accompanied by an anomaly of the conductivity for crystals oriented along the b-axis. The transition to the high-temperature fast ionic phase is observed at about 588 K for crystals oriented along [ 1011 and [ lOi] directions. The highest conductivity is observed for measurements perpendicular to the b-axis.

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