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Electric Properties of Macromolecules. IV. Determination of Electric and Optical Parameters from Saturation of Electric Birefringence in Solutions

✍ Scribed by O'Konski, Chester T; Yoshioka, Koshiro; Orttung, William H.


Book ID
120351167
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
837 KB
Volume
63
Category
Article
ISSN
0022-3654

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πŸ“œ SIMILAR VOLUMES


Electric properties of macromolecules. I
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## Abstract We first calculate the steady‐state birefringence, expressed in the form of specific Kerr constant, __K__~sp~, of rigid, bent‐rod macromolecules. Equations are derived for __K__~sp~ as a function of the geometric and electro‐optical parameters. We also consider flexibly hinged rods and

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Flow birefringence (FBR) and electric birefringence (EBR) have been investigated for dilute solutions of a number of fractions of cyclolinear (ladder) polychlorophenylsilsesquioxane (CLChPhS). FBR and EBR are negative in sign and their characteristic values increase with molecular weight in accordan