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Electric field effects on nuclear spin–spin coupling tensors and chiral discrimination via NMR spectroscopy

✍ Scribed by Gabriel I. Pagola; Marta B. Ferraro; Stefano Pelloni; Paolo Lazzeretti; Stephan P. A. Sauer

Publisher: Springer
Year: 2010
Tongue: English
Weight: 316 KB
Volume: 129
Category: Article
ISSN: 1432-2234
DOI: 10.1007/s00214-010-0851-2

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Erratum to: Electric field effects on nu

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Intramolecular electric field effect on a 1J(C,H) NMR spin–spin coupling constant. an experimental and theoretical study

✍ Dora G. de Kowalewski; Valdemar J. Kowalewski; Juan E. Peralta; Gernot Eskuche; 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 116 KB

An experimental study of the e †ects of intramolecular electric Ðelds on 1J(C,H) coupling constants involving a formyl proton in a series of 5-X-salicylaldehydes is reported. The particularly large electric Ðeld component along the bond, calculated for leads to a measured substituent e †ect of 7.36