✦ LIBER ✦

Electric field effects on kinetics of electron transfer reactions: connection between experiment and theory

✍ Scribed by Stefan Franzen; Kaiqin Lao; Steven G. Boxer

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 835 KB
Volume: 197
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(92)85789-d

No coin nor oath required. For personal study only.

✦ Synopsis

The dependence of the rate constant for electron transfer on energy can be systematically studied by measuring kinetics in an applied electric field. General relationships are developed between observed electric-field-modulated kinetics and theoretical expressions for the electron transfer rate constant, including both the energy dependence of the nuclear (Franck-Condon) and superexchange electronic factors. The technique described here augments the well-known approach of using chemical substitution of donors and acceptors as a probe of the dependence of rate on energy.

📜 SIMILAR VOLUMES

Kinetic salt effects on the outer sphere

Kinetic salt effects on the outer sphere electron transfer reaction between hexacyanoferrate(II) and 4-pyridinecarboxylatopentammine cobalt(III)

✍ P. LÓPez; E. Muñ;Oz; F. SáNchez; M. Galán 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 529 KB

A study is made of the kinetic salt effects upon the outer-sphere electron transfer reaction between hexacyanoferrate(I1) and 4-pyridinecarboxylatopentaamminecobalt(III~. The observed salts effects are analyzed, taking into account the possible association of the reactants with the ions of the suppo

Magnetic field effects on the photoinduc

Magnetic field effects on the photoinduced electron-transfer reaction of 1-acetonaphthone and diphenylamine in micellar solution

✍ Yoshifumi Tanimoto; Masanari Takayama; Michiya Itoh; Ryoichi Nakagaki; Saburo Na 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 393 KB

Kinetics of the electron transfer cross-

Kinetics of the electron transfer cross-reaction between Os(bpy)33+ incorporated in Nafion® coatings on electrodes and IrCl63− dissolved in solution: Effects of changes in Donnan potentials on electron transfer rates

✍ Youqin Xie; Fred C. Anson 📂 Article 📅 1993 🏛 Elsevier 🌐 English ⚖ 671 KB

ChemInform Abstract: Redox Reactions of

ChemInform Abstract: Redox Reactions of Heme-Containing Metalloproteins: Dynamic Effects of Self-Assembled Monolayers on Thermodynamics and Kinetics of Cytochrome c Electron-Transfer Reactions

✍ Milan Fedurco 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 26 KB 👁 2 views

Effects of nonionic micellar aggregates

Effects of nonionic micellar aggregates on the electron transfer reaction between l-glutamic acid and gold(III) complexes

✍ Pratik K. Sen; Nasimul Gani; Jayanta K. Midya; Biswajit Pal 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 457 KB

## Abstract The effect of nonionic micelles of Triton X‐100 on the oxidative decarboxylation of l‐glutamic acid by chloroaurate(III) complexes has been investigated in acetate buffer medium. The reaction is first order with respect to Au(III), but a complex order with respect to glutamate. H^+^ ion

On the effect of adsorbed substances und

On the effect of adsorbed substances undergoing interfacial rearrangements on the kinetics of ion and electron-transfer reactions: The case of n-hexadecyltributylphosphonium bromide

✍ A. Anastopoulos; M. Kaisheva 📂 Article 📅 1991 🏛 Elsevier Science ⚖ 420 KB