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Electric dipole transition moments between the 2Σ+u and 2Σ+g states of the He+2 ion

✍ Scribed by Aristophanes Metropoulos; Yan Li; Gerhard Hirsch; Robert J. Buenker

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
526 KB
Volume
198
Category
Article
ISSN
0009-2614

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✦ Synopsis

The electric dipole transition moments of the He; molecular ion between its two lowest 'X: states and its first six excited %+ states are computed at various internuclear distances between 0.8 and 4.0 a,. The results are obtained with two different A0 ba8sis sets at the multireference CI level of treatment and show strong variations in the regions of various avoided crossings of the 'Xl states. Predictions of the radiative transition probabilities between various He: vibrational levels in several '2: -'Z: band systems are made on this basis.

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