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Eine ungewöhnliche Addition von 1,2-Alkadienyliden-Carbenen an 1,3-Diene; 1,4-Addition an starre und flexible 1,3-Diene

✍ Scribed by Hikaru Sugita; Dr. Kazuhiko Mizuno; Toshiki Mori; Dr. Kakuzo Isagawa; Prof. Dr. Yoshio Otsuji

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
334 KB
Volume
103
Category
Article
ISSN
0044-8249

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ses. Their relative total energies are 0, 0.4, 4.4 and -3.6 kcalmol-I , respectively.1111 Although the difference in energy between the (q2-0,C-HNCO)(q2-C,N-HNCO) and (q2-C,N-HNCO), isomers is small, the calculations are inconsistent with the observed structure. Next, we used molecular mechanics ca