Ein neues Phosphorsulfid mit Adamantangerüst: δ-P4S7

✍ Scribed by Heike Nowottnick; Roger Blachnik

• Publisher: John Wiley and Sons
• Year: 2000
• Tongue: German
• Weight: 64 KB
• Volume: 626
• Category: Article
• ISSN: 0372-7874
• DOI: 10.1002/(sici)1521-3749(200003)626:3<611::aid-zaac611>3.0.co;2-o

✦ Synopsis

By sulfur abstraction from a-P 4 S 9 /P 4 S 10 with triphenylphosphine a new phosphorus sulfide d-P 4 S 7 with adamantane skeleton and an additional sulfur in exo-position was identified in CS 2 -solution by 31 P-NMR spectroscopy. Product distribution and 31 P-NMR parameter are given.