Chiral diamines. Part 3: Effect of ligan
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Kenneth B. Wiberg; William F. Bailey
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Article
📅
2000
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Elsevier Science
🌐
French
⚖ 320 KB
The deprotonation N-Boc-pyrrolidine by i-PrLi-(S,S)-1,2-bis(N,N-dimethylamino)cyclohexane has been studied at the HF/3-21G and B3P86/6-31G\* theoretical levels. The two lowest energy complexes of the N-Boc-pyrrolidine-i-PrLi-diamine ligand, as well as the transition states leading to proton transfer