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Efficient Transfer Hydrogenation Using Iridium and Rhodium Complexes of Benzannulated N-Heterocyclic Carbenes

✍ Scribed by Hayati Türkmen; Tania Pape; F. Ekkehardt Hahn; Bekir Çetinkaya

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 305 KB
Volume: 2008
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200800715

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## Abstract A novel chelated ferrocene‐based planar chiral N‐heterocyclic carbene‐Rh(I) complex was synthesized by a simple method. It was applied to the asymmetric transfer hydrogenation of prochiral ketones. Enantioselectivities of up to 67% ee were observed. Copyright © 2009 John Wiley & Sons, L