Efficient Tandem Process for the Catalytic Deprotection of N-Allyl Amides and Lactams in Aqueous Media: A Novel Application of the Bis(allyl)-Ruthenium(IV) Catalysts [Ru(η3:η2:η3-C12 H18)Cl2] and [{Ru(η3:η3-C10H16) (μ-Cl)Cl}2].

Efficient Tandem Process for the Catalyt

Efficient Tandem Process for the Catalytic Deprotection of N-Allyl Amides and Lactams in Aqueous Media: A Novel Application of the Bis(allyl)–Ruthenium(IV) Catalysts [Ru(η3:η2:η3-C12H18)Cl2] and [{Ru(η3:η3-C10H16)(μ-Cl)Cl}2]

✍ Victorio Cadierno; José Gimeno; Noel Nebra 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 105 KB 👁 2 views

## Abstract An operationally simple and highly efficient methodology for the removal of the allyl protecting group in amides and lactams has been developed by using the commercially available bis(allyl)–ruthenium(IV) catalysts [Ru(η^3^:η^2^:η^3^‐C~12~H~18~)Cl~2~] (C~12~H~18~=dodeca‐2,6,10‐triene‐1,