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Efficient Synthesis of Six-Membered Ring D Analogues of the Pentacyclic Alkaloid Cephalotaxine by Two Palladium-Catalyzed Reactions

✍ Scribed by Lutz F. Tietze; Hartmut Schirok; Michael Wöhrmann; Klaus Schrader


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
488 KB
Volume
2000
Category
Article
ISSN
1434-193X

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✦ Synopsis


D-homo-Cephalotaxine analogues 19 and 23 have been prepared by intramolecular Heck reactions of 12 and 22. The substrates 12 and 22 were obtained by alkylation and acyl- [a]