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Efficient synthesis of pyrrolizidine and indolizidine derivatives using nickel-catalyzed cyclization of 1,3-diene and aldehyde: Formal total synthesis of (−)-Elaeokanine C

✍ Scribed by Yoshihiro Sato; Nozomi Saito; Miwako Mori

Book ID: 104257144
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 226 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00782-x

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✦ Synopsis

Pyrrolizidine and indolizidine skeletons were successfully constructed by nickel-catalyzed cyclization of 1,3-diene and aldehyde in a chain. A formal total synthesis of an Elaeocarpus alkaloid, (-)-Elaeokanine C, in the naturally occurring form was achieved using this cyclization.

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