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Efficient synthesis of phosphorus-containing dendrimers capped with isosteric functions of amino-bismethylene phosphonic acids

✍ Scribed by Olivier Rolland; Cédric-Olivier Turrin; Gérard Bacquet; Remy Poupot; Mary Poupot; Anne-Marie Caminade; Jean-Pierre Majoral


Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
431 KB
Volume
50
Category
Article
ISSN
0040-4039

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✦ Synopsis


An efficient synthetic strategy to synthesize phosphorus-containing dendrimers capped with isosteric acid functions derived from tyramine is described. The method is demonstrated on a first generation dendrimer that can be easily capped with 12 amino(bismethylene) sulfonic acids and amino(bismethylene) carboxylic acids that are strict analogs of the corresponding amino(bismethylene) phosphonic acids.