Efficient synthesis of phenalenone derivatives by rhodium(II)-catalyzed reactions
β Scribed by Yong Rok Lee; Jung Yup Suk
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 182 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
An ecient synthesis of phenalenone derivatives is achieved by rhodium(II)-catalyzed reactions of 2-diazo-1H-1,3-phenalenedione with a variety of substrates in moderate yields. This method also provides a rapid route to biologically interesting polycycles and heterocycles.
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An efficient synthesis of oxindoles is achieved from a thermal and rhodium(H)-catalyzed Wolff rearrangement of diazoquinolinediones in moderate yields, 0 1999 Elsevier Science Ltd. All rights reserved. Oxindoles and their derivatives are very important compounds as synthetic intermediates of natura
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