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Efficient Synthesis of Novel Bis(dipyrromethanes) with Versatile Linkers via Indium(III) Chloride-Catalyzed Condensation of Pyrrole and Dialdehydes

✍ Scribed by Hongbin Zhao; Junxu Liao; Jingheng Ning; Yujia Xie; Yingjie Cao; Liang Chen; Deliang Yang; Bangying Wang


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
220 KB
Volume
352
Category
Article
ISSN
1615-4150

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✦ Synopsis


Abstract

A new efficient and mild protocol for synthesizing a series of novel bis(dipyrromethanes) with versatile arylene linkers through an indi‐ um(III) chloride‐catalyzed condensation reaction between various dialdehydes and pyrrole has been developed. This protocol is applicable to constructing a variety of bis(dipyrromethanes) with diverse functional linkers, which provides a powerful route to construct libraries of functionalized porphyrin dimers and even multiporphyrin arrays.