Efficient Synthesis of Naphthalene-Fused Dilactam Crown Ethers.
โ Scribed by Hossein Eshghi; Mehdi Mirzaei; Hadi Esmaily-Shahry
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 17 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The sulfuric acid-promoted reaction of benzo-15-crown-5 O) and benzo-18-crown-6 (6) with aliphatic aldehydes, leading to the formation of anthracene crown et~rs, was studied. A substantial substiment effect on the reaction comse was found. For the isdmtyi group the highest yield was obtained, while
Che synthesis and chemistry of macrocyclic polyethers are currently receiving a great deal of attention. Very recently Cram and co-workers 132 have reported the synthesis of two crown ethers (3,~ and QJ). We have prepared two series of novel crown ethers in which respectively, the 1,3and 2,5-positio
The Synthesis of Anthracene Crown Ethers Derived from Benzo-Crown Ethers. -A method to obtain anthracene crown ethers starting from benzo-15-crown-5-ether and benzo-18-crown-6-ether and various aldehydes is described. The yield strictly depends on the aldehyde. Cyclohexanone leads to a new class of