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Efficient Synthesis of Doubly Connected Primary Face-to-Face Cyclodextrin Homo-Dimers

✍ Scribed by Thomas Lecourt; Jean-Maurice Mallet; Pierre Sinaÿ


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
182 KB
Volume
2003
Category
Article
ISSN
1434-193X

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✦ Synopsis


Abstract

“Head‐to‐head” type α‐ and β‐cyclodextrin homo‐dimers in which the two primary rims are doubly ligated through alkyl chains have been synthesised in high yield by acyclic diene metathesis (ADM), followed by ring‐closing metathesis (RCM). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)


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Symmetrical doubly connected head-to-hea
✍ Thomas Lecourt; Jean-Maurice Mallet; Pierre Sinaÿ 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 148 KB

A 'head-to-head' type a-cyclodextrin dimer, wherein the two primary rims are doubly ligated through alkyl chains, is synthesised in high yield using acyclic diene metathesis (ADM) followed by ring closing metathesis (RCM).